This work studies heat transfer mechanisms during ultrafast laser heat
ing of metals from a microscopic point of view. The heating process is
composed of three processes: the deposition of radiation energy on el
ectrons, the transport of energy by electrons, and the heating of the
material lattice through electron-lattice interactions. The Boltzmann
transport equation is used to model the transport of electrons and ele
ctron-lattice interactions. The scattering term of the Boltzmann equat
ion is evaluated from quantum mechanical considerations, which shows t
he different contributions of the elastic and inelastic electron-latti
ce scattering processes on energy transport. By solving the Boltzmann
equation, a hyperbolic two-step radiation heating model is rigorously
established. It reveals the hyperbolic nature of energy flux carried b
y electrons and the nonequilibrium between electrons and the lattice d
uring fast heating processes. Predictions from the current model agree
with available experimental data during subpicosecond laser heating.