Micro-Raman scattering by highly oriented crystalline aluminum nitride
has been measured. Phonon modes in AlN were identified in different s
cattering geometry configurations and scattering polarizations. The ph
onon modes revealed that aluminum nitride films are highly oriented wi
th the wurtzite c-axis direction normal to the film plane. The Raman s
cattering modes are broadened and shifted due to grain boundaries and
other defects in the films. The defect scattering was analysed using t
he phonon confinement model. These results were compared with results
obtained from X-ray diffraction powder patterns and high-resolution tr
ansmission electron microscopy.