NEW HOMOCHIRAL BINAPHTHOL-MODIFIED ORGANOLANTHANIDE REAGENTS FOR THE ENANTIOSELECTIVE ADDITION TO ALDEHYDES

Authors
CHIBALE K GREEVES N LYFORD L PEASE JE
Citation
K. Chibale et al., NEW HOMOCHIRAL BINAPHTHOL-MODIFIED ORGANOLANTHANIDE REAGENTS FOR THE ENANTIOSELECTIVE ADDITION TO ALDEHYDES, Tetrahedron : asymmetry, 4(12), 1993, pp. 2407-2410
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
4
Issue
12
Year of publication
1993
Pages
2407 - 2410
Database
ISI
SICI code
0957-4166(1993)4:12<2407:NHBORF>2.0.ZU;2-0
Abstract
Optically active secondary alcohols were obtained in high chemical yie ld and optical purity (up to 85% ee) from the lanthanide-mediated enan tioselective addition of alkyl nucleophiles to aromatic aldehydes.