E. Paezmozo et al., COBALT PHTHALOCYANINE ENCAPSULATED IN Y-ZEOLITE - A PHYSICOCHEMICAL STUDY, Journal of physical chemistry, 97(49), 1993, pp. 12819-12827
Cobalt phthalocyanine was synthesized within the cavities of Y zeolite
s and was characterized in all the steps of the synthesis and purifica
tion procedures by elemental analysis, Fourier transform infrared spec
troscopy, UV-visible spectroscopy, X-ray photoelectron spectroscopy, s
urface analysis, thermogravimetric analysis, differential thermal anal
ysis, X-ray diffraction, and conventional transmission and high-resolu
tion electron microscopy. Besides the cobalt phthalocyanine (12% in we
ight), other nitrogen-containing compounds (2% in weight) are associat
ed to the acidic sites of the zeolite and/or axially coordinated to th
e cobalt complex.