Cp. Ballance et al., INTERLOPER RESONANCES IN THE (3)SIGMA(-)(U) TRANSITORY STATES OF O-2, Journal of physics. B, Atomic molecular and optical physics, 31(15), 1998, pp. 655-665
We have undertaken a detailed study of the various Rydberg resonance s
eries found in the (3)Sigma(u)(-) symmetry for electron collisions wit
h molecular oxygen ions. A five-state valence CI approximation is used
in our expansion of the target molecular states within the ab initio
close-coupling R-matrix approach to calculate the relevant eigenphase
sum and associated cross sections. Rydberg resonances series are detec
ted, identified and analysed. An analysis of our results indicates the
presence of 4p sigma(u), 5p sigma(u), 6p sigma(u), 3d pi(g) and 4f si
gma(u) interloper resonances in the (3)Sigma(u)(-) scattering symmetry
which have been assigned to the appropriate molecular oxygen cation t
hreshold. The presence of these interlopers is seen to cause a perturb
ation on the relevant spectral series disrupting the regular Rydberg s
eries pattern. The results for several low-lying members of each Rydbe
rg series are analysed in detail and compared with the available theor
etical and experimental work.