ADDUCTS OF 4-T-BUTYLPHENOXO COMPLEXES OF OXOVANADIUM(V) WITH 2-CYANOPYRIDINE, 3-CYANOPYRIDINE AND 4-CYANOPYRIDINE

Authors
MALHOTRA KC BALA B SHARMA N BHATT SS CHAUDHRY SC
Citation
Kc. Malhotra et al., ADDUCTS OF 4-T-BUTYLPHENOXO COMPLEXES OF OXOVANADIUM(V) WITH 2-CYANOPYRIDINE, 3-CYANOPYRIDINE AND 4-CYANOPYRIDINE, Journal of the Indian Chemical Society, 75(3), 1998, pp. 137-139
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of the Indian Chemical Society → ACNP
ISSN journal
00194522
Volume
75
Issue
3
Year of publication
1998
Pages
137 - 139
Database
ISI
SICI code
0019-4522(1998)75:3<137:AO4COO>2.0.ZU;2-K
Abstract
4-t-Butylphenoxo-complexes of oxovanadium(v) of composition VOCl3-x(OC 6H4But-4)(x), where x = 1 --> 3, react with 2-, 3- and 4-cyanopyridine s to give adducts of varying composition. 2-Cyanopyridine forms adduct of 1 : 1 composition, coordinating simultaneously through pyridine as well as nitrile nitrogens of the ligand, while 3- and 4-cyanopyridine s forms adducts of 1 : 2 composition (metal : ligand) coordinating thr ough only pyridine nitrogen of the ligand.