METAL CENTERS LINKED BY BIS(IMIDO)PHENYLENE LIGANDS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF 1,3-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)] AND 1,4-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)]

Authors
HOGARTH G MALLORS RL NORMAN T
Citation
G. Hogarth et al., METAL CENTERS LINKED BY BIS(IMIDO)PHENYLENE LIGANDS - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURES OF 1,3-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)] AND 1,4-[(CIS,TRANS-WCL2(PH2PME)2(CO))2(MU-NC6H4N)], Journal of the Chemical Society, Chemical Communications, (23), 1993, pp. 1721-1723
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
23
Year of publication
1993
Pages
1721 - 1723
Database
ISI
SICI code
0022-4936(1993):23<1721:MCLBBL>2.0.ZU;2-I
Abstract
Addition of 2 equiv. of [WCl2(Ph2PMO)4] to 1,3- or 1,4-phenylenediisoc yanate results in rapid oxidative addition of isocyanate affording the bis(imido)phenylene bridged tungsten(iv) complexes 1,3- and 1,4-[{cis ,trans-WCl2(Ph2PMe)2(CO))2(mu-NC6H4N)], respectively; both have been c haracterised by X-ray crystallography.