THE LINEAR MNII COMPLEX MN3(5-NO2-SALIMH)2(OAC)4 PROVIDES AN ALTERNATIVE STRUCTURE TYPE FOR THE CARBOXYLATE SHIFT IN PROTEINS

Authors
BALDWIN MJ KAMPF JW PECORARO VL
Citation
Mj. Baldwin et al., THE LINEAR MNII COMPLEX MN3(5-NO2-SALIMH)2(OAC)4 PROVIDES AN ALTERNATIVE STRUCTURE TYPE FOR THE CARBOXYLATE SHIFT IN PROTEINS, Journal of the Chemical Society, Chemical Communications, (23), 1993, pp. 1741-1743
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
23
Year of publication
1993
Pages
1741 - 1743
Database
ISI
SICI code
0022-4936(1993):23<1741:TLMCMP>2.0.ZU;2-P
Abstract
The title complex {where 5-NO2-salimH-2 = 4-[2-(5-NO2-salicylideneimin e)ethyl]imidazole} has been structurally characterized and is the firs t mu-phenolato, mu-carboxylato-O, mu-carboxylato-O,O' type model for t he 'carboxylate shift' in polymanganese and polyiron enzymes.