RUTHENIUM DIHYDROGEN COMPLEXES VIA C-H CLEAVAGE IN ALK-1-YNES - CRYSTAL-STRUCTURE OF [RU(H2)(C-EQUIVALENT-TO-CPH)(DIPPE)2][BPH4] [DIPPE = 1,2-BIS(DIISOPROPYLPHOSPHINO)ETHANE]

Authors
TENORIO MJ PUERTA MC VALERGA P
Citation
Mj. Tenorio et al., RUTHENIUM DIHYDROGEN COMPLEXES VIA C-H CLEAVAGE IN ALK-1-YNES - CRYSTAL-STRUCTURE OF [RU(H2)(C-EQUIVALENT-TO-CPH)(DIPPE)2][BPH4] [DIPPE = 1,2-BIS(DIISOPROPYLPHOSPHINO)ETHANE], Journal of the Chemical Society, Chemical Communications, (23), 1993, pp. 1750-1751
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
23
Year of publication
1993
Pages
1750 - 1751
Database
ISI
SICI code
0022-4936(1993):23<1750:RDCVCC>2.0.ZU;2-E
Abstract
The reaction of the monohydride complex [RuH(dippe)2]+ with alk-1-ynes yields the dihydrogen complexes [Ru(H-2)(C=CR)(dippe)2]+ [R = Ph or C O2Me); the X-ray crystal structure of [Ru(H-2)(C=CPh)(dippe)2][BPh4] h as been determined, and represents the first structural report of an a lkynyl-dihydrogen complex.