A NEW ROUTE TO ALPHA-TRIALKYLSILYL ALDEHYDES - THE 1ST ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES

Authors
DUHAMEL L GRALAK J BOUYANZER A
Citation
L. Duhamel et al., A NEW ROUTE TO ALPHA-TRIALKYLSILYL ALDEHYDES - THE 1ST ISOLATION OF ALPHA-TRIMETHYLSILYL ALDEHYDES, Journal of the Chemical Society, Chemical Communications, (23), 1993, pp. 1763-1765
Citations number
17
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
23
Year of publication
1993
Pages
1763 - 1765
Database
ISI
SICI code
0022-4936(1993):23<1763:ANRTAA>2.0.ZU;2-V
Abstract
Alpha-Trimethylsilyl and alpha-triethylsilyl aldehydes 6 were obtained from trimethylsilyl and triethylsilyl beta-bromo enol ethers 1, using a bromine-lithium exchange and a 1-3 migration of the trialkylsilyl g roup.