SYNTHESIS, STRUCTURE AND PROPERTIES OF A NEW VANADYL PHENOLATE DERIVATIVE AS A MODEL FOR THE VANADIUM(IV) TRANSFERRINS

Authors
NEVES A CECCATTO AS ERASMUSBUHR C GEHRING S HAASE W PAULUS H NASCIMENTO OR BATISTA AA
Citation
A. Neves et al., SYNTHESIS, STRUCTURE AND PROPERTIES OF A NEW VANADYL PHENOLATE DERIVATIVE AS A MODEL FOR THE VANADIUM(IV) TRANSFERRINS, Journal of the Chemical Society, Chemical Communications, (23), 1993, pp. 1782-1784
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
23
Year of publication
1993
Pages
1782 - 1784
Database
ISI
SICI code
0022-4936(1993):23<1782:SSAPOA>2.0.ZU;2-8
Abstract
The synthesis, and the X-ray crystal structure, spectroeletrochemical and spectroscopic properties of [OV(IV)(bbpen)] [H-2bbpen = ybenzyl)-N ,N'-bis(2-pyridylmethyl)ethylenediamime] are reported; this complex is the first VO2+ species that exhibits similar UV-VIS and EPR propertie s to those detected in VO2+ transferrins.