The Nd2-xSrxNiO4+delta (0 less-than-or-equal-to x less-than-or-equal-t
o 1) system prepared under different surrounding atmospheres has been
studied by means of powder X-ray diffraction and thermogravimetric ana
lysis. The accurate control of oxygen content in this system leads to
three different K2NiF4-related structural types which are also depende
nt upon the Sr content.