EXPERIMENTAL-EVIDENCE FOR A [2-PROMOTED FORMATION OF ALPHA,BETA-UNSATURATED ESTERS FROM ETHOXYACETYLENE AND ALDEHYDES - SYNTHESIS AND CHARACTERIZATION OF 4-ETHOXYOXETES(2] MECHANISM IN THE LEWIS ACID)

Authors
OBLIN M PARRAIN JL RAJZMANN M PONS JM
Citation
M. Oblin et al., EXPERIMENTAL-EVIDENCE FOR A [2-PROMOTED FORMATION OF ALPHA,BETA-UNSATURATED ESTERS FROM ETHOXYACETYLENE AND ALDEHYDES - SYNTHESIS AND CHARACTERIZATION OF 4-ETHOXYOXETES(2] MECHANISM IN THE LEWIS ACID), Chemical communications, (16), 1998, pp. 1619-1620
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1998
Pages
1619 - 1620
Database
ISI
SICI code
1359-7345(1998):16<1619:EFA[FO>2.0.ZU;2-J
Abstract
4-Ethoxy-2H-oxetes 3a-c were prepared from ethoxyacetylene and alkoxy aldehydes la-e through MgBr2-Et2O promoted [2 + 2] cycloaddition react ion and were characterized at room temperature; their synthesis, which could occur via the formation of a chelate, establishes cycloaddition as the initial step in the formation of alpha,beta-unsaturated esters 4a-c.