DIRECTED REACTIVITY AT A VANADIUM(II) THIOLATE CENTER - SYNTHESIS ANDSTRUCTURE OF A NOVEL VANADIUM THIOLATE COMPLEX AND ITS REACTION-PRODUCT WITH AZOBENZENE

Authors
DAVIS JA DAVIE CP SABLE DB ARMSTRONG WH
Citation
Ja. Davis et al., DIRECTED REACTIVITY AT A VANADIUM(II) THIOLATE CENTER - SYNTHESIS ANDSTRUCTURE OF A NOVEL VANADIUM THIOLATE COMPLEX AND ITS REACTION-PRODUCT WITH AZOBENZENE, Chemical communications, (16), 1998, pp. 1649-1650
Citations number
30
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1998
Pages
1649 - 1650
Database
ISI
SICI code
1359-7345(1998):16<1649:DRAAVT>2.0.ZU;2-P
Abstract
The vanadium(II) thiolate complex [V(tmeda)(DCTP)(2)] [DCTP = 2,6-dich lorothiophenolate; tmeda = N,N,N',N'-tetramethylethylenediamine] is ob tained by the reaction of 2 equiv, of LiDCTP with [VCl2(tmeda)(2)] and reacts with azobenzene to yield the imido-containing complex [V(tmeda )(DCTP)(2)(=NPh)].