ULTRA RIGID CROSS-BRIDGED TETRAAZAMACROCYCLES AS LIGANDS - THE CHALLENGE AND THE SOLUTION

Authors
HUBIN TJ MCCORMICK JM COLLINSON SR ALCOCK NW BUSCH DH
Citation
Tj. Hubin et al., ULTRA RIGID CROSS-BRIDGED TETRAAZAMACROCYCLES AS LIGANDS - THE CHALLENGE AND THE SOLUTION, Chemical communications, (16), 1998, pp. 1675-1676
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1998
Pages
1675 - 1676
Database
ISI
SICI code
1359-7345(1998):16<1675:URCTAL>2.0.ZU;2-Q
Abstract
The challenge to metal ion binding that is represented by the proton-s ponge nature of two-carbon cross-bridged tetraazamacrocycles has been overcome and a general method developed for the synthesis of their tra nsiton, and other, metal complexes; these ultra-rigid ligands form com plexes having remarkable kinetic stabilities.