REACTION IN SUPERCRITICAL CO2 - AN INTERCALATION OF 4-PHENYLAZOANILINE BETWEEN LAYERS OF MONTMORILLONITE PILLARED WITH TETRAMETHYLAMMONIUM IONS

Authors
ISHII R WADA H OOI K
Citation
R. Ishii et al., REACTION IN SUPERCRITICAL CO2 - AN INTERCALATION OF 4-PHENYLAZOANILINE BETWEEN LAYERS OF MONTMORILLONITE PILLARED WITH TETRAMETHYLAMMONIUM IONS, Chemical communications, (16), 1998, pp. 1705-1706
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1998
Pages
1705 - 1706
Database
ISI
SICI code
1359-7345(1998):16<1705:RISC-A>2.0.ZU;2-7
Abstract
The intercalation reaction of 4-phenylazoaniline into montmorillonite pillared with tetramethylammonium ions has been performed successfully in supercritical CO2 (SCC) at T = 313 K (P = 15 MPa), demonstrating t hat SCC is a better medium than organic solutions for intercalating la rge amounts of guest molecules into a host compound without the contam ination of solvent.