HYDROTHERMAL SYNTHESIS AND STRUCTURE OF A 3-DIMENSIONAL OPEN-FRAMEWORK COBALT MOLYBDENUM(VI) PHOSPHATE-CONTAINING ETHYLENEDIAMMONIUM IONS -(C2H9N2)(6)[CO3MO4P4O28]
Jj. Lu et al., HYDROTHERMAL SYNTHESIS AND STRUCTURE OF A 3-DIMENSIONAL OPEN-FRAMEWORK COBALT MOLYBDENUM(VI) PHOSPHATE-CONTAINING ETHYLENEDIAMMONIUM IONS -(C2H9N2)(6)[CO3MO4P4O28], Chemical communications, (16), 1998, pp. 1709-1710
The first microporous cobalt molybdenum(VI) phosphate, crystallised un
der hydrothermal conditions, is constructed from unique CoMo2P tetrahe
dral units connected by CoO4 tetrahedra and by sharing corners; the fr
amework contains interlocking cavity units and unusual 7-ring intersec
ting channels that are filled with charge-compensating ethylenediammon
ium ions.