A NEW STRUCTURAL TYPE IN IRON CARBOXYLATE CLUSTER CHEMISTRY VIA USE OF BIS-BIPYRIDINE LIGANDS - [FE6O4CL4(O2CPH)(4)L-2][FECL4](2)

Authors
GRANT CM KNAPP MJ HUFFMAN JC HENDRICKSON DN CHRISTOU G
Citation
Cm. Grant et al., A NEW STRUCTURAL TYPE IN IRON CARBOXYLATE CLUSTER CHEMISTRY VIA USE OF BIS-BIPYRIDINE LIGANDS - [FE6O4CL4(O2CPH)(4)L-2][FECL4](2), Chemical communications, (16), 1998, pp. 1753-1754
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
16
Year of publication
1998
Pages
1753 - 1754
Database
ISI
SICI code
1359-7345(1998):16<1753:ANSTII>2.0.ZU;2-D
Abstract
The reaction between FeCl3, NaO2CPh and L [L = 1,2-bis(2,2'-bipyridyl- 6-yl)ethane] in MeCN gives the title complex 1 whose cation contains a n unusual [Fe-6(mu(3)-O)(4)](10+) core, whereas in MeOH the dinuclear complex [Fe-2(OMe)(2-)Cl-2(O2CPh)L][FeCl4] 2 is obtained; magnetic stu dies indicate that the cations of 1 and 2 both have S = 0 ground state s, consistent with the expected antiferromagnetic exchange interaction s.