Modeling was performed to simulate ground water ow through reactive ba
rriers of lower hydraulic conductivity than the surrounding aquifer to
determine the plume capture widths. As a plume approaches such a barr
ier, it spreads laterally. Therefore, to intercept an entire plume, th
e barrier must be wider than the upgradient width of the undisturbed p
lume. The results indicate that, for practical values of barrier thick
ness and plume width, hydraulic conductivities ten-fold less than that
of the aquifer can be accommodated by making the width of the barrier
approximately 20% greater than the upgradient width of the plume. Bar
rier hydraulic conductivities one-hundred-fold less than that of the a
quifer may require barrier widths up to twice the width of the upgradi
ent plume for plumes 100 feet wide (33 m) and as little as 1.1 times f
or plumes 1000 feet wide (325 m). The results presented here lend supp
ort to the view that novel emplacement methods that create zones of sl
ightly lower hydraulic conductivity than the native aquifer may be via
ble alternatives to the excavation-and-backfill approaches which have
thus far been used for installing permeable reactive barriers.