In this work, the band offsets at the Ga0.5In0.5P/AlxGa0.5-xIn0.5P het
erojunction lattice matched to (001) GaAs was calculated over the whol
e range of aluminum composition from x=0.0 to 0.5 using the first-prin
ciples pseudopotential method with virtual crystal approximation. The
valence band offset, VBO, varies with x as VBO = 0.433x eV, while the
inferred conduction band offset CBO at Gamma minimum (bandgap differen
ce minus the valence band offset) varies in x as CBOGamma = 0.787x eV.
Our results are in good agreement with the experimental data. (C) 199
8 American Institute of Physics. [S0003-6951(98)02034-8]