A STEREOSELECTIVE ACCESS TO FUNCTIONAL DIENES CONTAINING A TRIFLUOROMETHYL GROUP VIA STILLE CROSS-COUPLING OF ETHYL 4,4,4-TRIFLUORO-3-IODOBUTENOATE

Authors
PRIE G THIBONNET J ABARBRI M DUCHENE A PARRAIN JL
Citation
G. Prie et al., A STEREOSELECTIVE ACCESS TO FUNCTIONAL DIENES CONTAINING A TRIFLUOROMETHYL GROUP VIA STILLE CROSS-COUPLING OF ETHYL 4,4,4-TRIFLUORO-3-IODOBUTENOATE, Synlett, (8), 1998, pp. 839
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
8
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):8<839:ASATFD>2.0.ZU;2-N
Abstract
Stereoselective construction of 3-trifluoromethyl conjugated dienoates or enynoates was achieved from ethyl (Z)-4,4,4-trifluoro-3-iodobuteno ate and alkenyltin or alkynyltin reagents through the Stille reaction. Reduction of ethyl 3-trifluoromethyldienoates using DIBAL-H selective ly afforded allylic alcohols.