ASYMMETRIC-SYNTHESIS XXVIII - NOVEL CHIRAL AMINOPHOSPHINE PHOSPHINITELIGAND AND ITS APPLICATION IN HOMOGENEOUS CATALYTIC ASYMMETRIC HYDROGENATION OF DEHYDROAMINO ACID-DERIVATIVES

Authors
MI AQ LOU RG JIANG YZ DENG JG QIN Y FU FM HU WH CHAN ASC
Citation
Aq. Mi et al., ASYMMETRIC-SYNTHESIS XXVIII - NOVEL CHIRAL AMINOPHOSPHINE PHOSPHINITELIGAND AND ITS APPLICATION IN HOMOGENEOUS CATALYTIC ASYMMETRIC HYDROGENATION OF DEHYDROAMINO ACID-DERIVATIVES, Synlett, (8), 1998, pp. 847
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
8
Year of publication
1998
Database
ISI
SICI code
0936-5214(1998):8<847:AX-NCA>2.0.ZU;2-B
Abstract
Novel chiral aminophosphine phosphinite, DPAMPP was designed and synth esized from (1S,2R)-1,2-diphenyl-2-aminoethanol. Its cationic rhodium complex has been found to be an excellent catalyst for enantioselectiv e hydrogenation of dehydroamino acids (more than 95.0%e.e.).