Portland cement with a low C(3)A content is sulphate resistant because
its hydration products react either not at all or only to small exten
t with sulphate ions. Blastfurnace cement with a high content of blast
furnace slag is sulphate resistant because on hydration it produces a
hardened cement paste into which the sulphate ions are virtually unabl
e to penetrate. Rapid tests are capable, with certain limitations, of
ranking cements in the correct order of sulphate resistance. However t
he scatter of the measured values in tests carried out in different te
sting laboratories is so large with all known methods that standardiza
tion is not a possibility. The experience gained when testing highly s
ulphate-resistant cements indicates that, with certain preconditions,
the addition of fly ash to concrete increases the sulphate resistance
and that a definitive assessment is only possible when the effect of t
he very slow progress of hydration of the fly ash, especially in the f
irst 28 days, has been clarified.