VALIDATION OF MILLIMETER-WAVE ATMOSPHERIC SOUNDER (MAS) OZONE MEASUREMENTS

This paper discusses the validation of measurements of O-3 distributio n in the Earth's atmosphere made by the Millimeter-wave Atmospheric So under (MAS), a component of NASA's ATLAS spacelab shuttle package. Mea surements of 184 GHz O-3 emission from the Earth's limb at tangent alt itudes between 20 and 80 km were made with a 50 channel radiometer hav ing a spectral resolution of 200 KHz. In three missions the emissions of O-3, H2O: ClO, and O-2 were measured between 70 degrees S and 70 de grees N latitudes. O-3 mixing ratio calculations and error analysis we re performed with the Rodgers optimal estimation method. Data binned i n 128 s batches yield mixing ratio profiles with an altitude resolutio n of 7 km at the O-3 peak and an estimated accuracy of 5%. Additional retrievals made with all data from each mission binned in 50 latitude zones yield mixing ratios with about 5 km altitude resolution and some what improved accuracy. Comparisons with coincident measurements from other space platforms indicate a general agreement within approximatel y 5%. The data are publicly available through the German Remote Sensin g Data Center.