Mr. Doi et al., PATTERN EVOLUTION OF CRYSTALLINE GE AGGREGATES DURING ANNEALING OF ANAL GE BILAYER FILM DEPOSITED ON A SIO2 SUBSTRATE/, Philosophical magazine letters, 78(3), 1998, pp. 241-245
When an Al/Ge bilayer film deposited on a SiO2 substrate is annealed a
t 373-398 K, Ge atoms diffuse out from the inner amorphous Ge layer an
d spread over the Free surface of the outer Al layer to form crystalli
ne Ge aggregates exhibiting complex substructures. Scanning electron m
icroscopy observations indicate that the activation energy for the pat
tern evolution of Ge aggregates on the free surface because of anneali
ng is 1.56 eV which is about half the activation energy for crystalliz
ation of amorphous Ge.