TRISKIS AND TETRAKIS( 1-METHYLCYTOSINE) COMPLEXES OF PT(II) - SYNTHESES AND X-RAY STRUCTURES OF [PT(1-MEC-N3)(3)CL](-MEC-N3)(4)](2+) COMPOUNDS() AND [PT(1)

Authors
HEGMANS A FREISINGER E ZANGRANDO E ASHFAR A HUBENER E APPLETON TG LIPPERT B
Citation
A. Hegmans et al., TRISKIS AND TETRAKIS( 1-METHYLCYTOSINE) COMPLEXES OF PT(II) - SYNTHESES AND X-RAY STRUCTURES OF [PT(1-MEC-N3)(3)CL](-MEC-N3)(4)](2+) COMPOUNDS() AND [PT(1), Inorganica Chimica Acta, 279(2), 1998, pp. 152-158
Citations number
35
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
279
Issue
2
Year of publication
1998
Pages
152 - 158
Database
ISI
SICI code
0020-1693(1998)279:2<152:TAT1CO>2.0.ZU;2-9
Abstract
Starting from K2PtCl4 and 1-methylcytosine (1-MeC), cationic [Pt(1-MeC )(3)Cl](+) (1) and [Pt(1-MeC)(4)](2+) (2) species have been prepared a nd isolated with various counter-ions. 1a (NO3-), 1b (ClO4-), 2b (NO3- ), and 2c (Cl-) have been characterized by X-ray crystallography. Pt b inding in 1 and 2 is through N3. The nucleobases display mutual head-t ail-head and head-tail-head-tail orientations in 1 and 2, respectively . The synthetic potential of the two complexes is briefly discussed. ( C) 1998 Elsevier Science S.A. All rights reserved.