B-Z CHEMICAL OSCILLATIONS IN NITRIC-ACID AND PHOSPHORIC-ACID MEDIUM WITH GALLIC ACID AS SUBSTRATE AND FERROIN AND MN(II) IONS AS CATALYST

Citation
Sc. Pal et Rs. Banerjee, B-Z CHEMICAL OSCILLATIONS IN NITRIC-ACID AND PHOSPHORIC-ACID MEDIUM WITH GALLIC ACID AS SUBSTRATE AND FERROIN AND MN(II) IONS AS CATALYST, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 37(6), 1998, pp. 550-554
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710 → ACNP
Volume
37
Issue
6
Year of publication
1998
Pages
550 - 554
Database
ISI
SICI code
0376-4710(1998)37:6<550:BCOINA>2.0.ZU;2-O
Abstract
Chemical oscillations have been studied both visually and potentiometr ically with gallic acid as substrate in a new acid medium, i.e., HNO3 medium with ferroin as catalyst. The oscillations are very much pronou nced. Studies have also been made in H3PO4 medium using Mn(II) ions as catalyst which is also a new combination. The oscillation parameters have been found to obey certain simple relations. A comparison has als o been made with previous studies in H2SO4 and HClO4 media.