X-RAY STRUCTURAL AND SPECTROSCOPIC STUDIES OF A MONONUCLEAR COPPER(II) COMPLEX WITH AXIAL AND EQUATORIAL PHENOLATE LIGATION

Authors
BANDYOPADHYAY P GHOSH P BHARADWAJ PK
Citation
P. Bandyopadhyay et al., X-RAY STRUCTURAL AND SPECTROSCOPIC STUDIES OF A MONONUCLEAR COPPER(II) COMPLEX WITH AXIAL AND EQUATORIAL PHENOLATE LIGATION, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 37(7), 1998, pp. 639-643
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical
ISSN journal
03764710 → ACNP
Volume
37
Issue
7
Year of publication
1998
Pages
639 - 643
Database
ISI
SICI code
0376-4710(1998)37:7<639:XSASSO>2.0.ZU;2-Y
Abstract
A tridentate Schiff base obtained by condensing salicylaldehyde with 2 -dimethylamino-ethylamine in 1:1 molar ratio readily forms a bis-compl ex with cupric perchlorate hexahydrate in methanol in the presence of KOH. The complex crystallizes from methanol in the monoclinic space gr oup P21/c with a = 11.221(3), b = 19.462(2), c = 13.062(3), beta = 109 .36(4)degrees, Z = 4, R = 0.050, R' = 0.045 and goodness-of-fit = 2.55 1.