A DINUCLEAR ZINC HYDROXIDE COMPLEX WHICH TRAPS ATMOSPHERIC CARBON-DIOXIDE - FORMATION OF A TRI-ZINC COMPLEX WITH A TRIPLY BRIDGING CARBONATE GROUP

Citation
Nn. Murthy et Kd. Karlin, A DINUCLEAR ZINC HYDROXIDE COMPLEX WHICH TRAPS ATMOSPHERIC CARBON-DIOXIDE - FORMATION OF A TRI-ZINC COMPLEX WITH A TRIPLY BRIDGING CARBONATE GROUP, Journal of the Chemical Society, Chemical Communications, (15), 1993, pp. 1236-1238
Citations number
27
Categorie Soggetti
Chemistry
ISSN journal
00224936
Issue
15
Year of publication
1993
Pages
1236 - 1238
Database
ISI
SICI code
0022-4936(1993):15<1236:ADZHCW>2.0.ZU;2-R
Abstract
Dinuclear di-mu-hydroxo zinc(II)complex 1, containing a tetradentate n itrogen ligand, readily absorbs atmospheric CO2 to form tri-zinc compl ex 2, containing an uncommon triply bridging carbonate group; the stru ctures of 1 and 2 have been established by X-ray crystallography.