[3-CYCLOADDITION REACTIONS OF THE PHOSPHA-ALKYNE, (BUCP)-C-T, WITH A TRANSITION-METAL TRISULFIDE CONTAINING TERMINAL THIO LIGANDS - SYNTHESES, CRYSTAL-STRUCTURES AND MOLECULAR-STRUCTURES OF [W(ETA(5)-(C5ME5)(S)((S2PCBU)-BU-T)](2) AND [W(ETA(5)-(C5ME5)(S)(S2C2PH2)](2)(2])

Authors
DARBELOFF SE HITCHCOCK PB NIXON JF NAGASAWA T KAWAGUCHI H TATSUMI K
Citation
Se. Darbeloff et al., [3-CYCLOADDITION REACTIONS OF THE PHOSPHA-ALKYNE, (BUCP)-C-T, WITH A TRANSITION-METAL TRISULFIDE CONTAINING TERMINAL THIO LIGANDS - SYNTHESES, CRYSTAL-STRUCTURES AND MOLECULAR-STRUCTURES OF [W(ETA(5)-(C5ME5)(S)((S2PCBU)-BU-T)](2) AND [W(ETA(5)-(C5ME5)(S)(S2C2PH2)](2)(2]), Journal of organometallic chemistry, 564(1-2), 1998, pp. 189-191
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
564
Issue
1-2
Year of publication
1998
Pages
189 - 191
Database
ISI
SICI code
0022-328X(1998)564:1-2<189:[ROTP(>2.0.ZU;2-S
Abstract
The trisulphido complex [PPh4][W(eta(5)-(C5Me5)(S)(3)], reacts with th e phospha-alkyne (BuCP)-C-t and O-2 to afford the dimeric complex [W(e ta(5)-(C5Me5)(S)((S2PCBu)-Bu-t)](2). Analogous reactions occur with th e alkyne Ph2C2 to give [W(eta(5)-(C5Me5)(S)(S2C2Ph2)](2). The molecula r structures of both complexes are presented and discussed. (C) 1998 E lsevier Science S.A. All rights reserved.