A NEW HONEYCOMB-LIKE MOLECULAR-COMPOUND - GD[C6H3(COO)(3)](H2O)(3)CENTER-DOT-1.5H(2)O

Authors
DAIGUEBONNE C GERAULT Y GUILLOU O LECERF A BOUBEKEUR K BATAIL P KAHN M KAHN O
Citation
C. Daiguebonne et al., A NEW HONEYCOMB-LIKE MOLECULAR-COMPOUND - GD[C6H3(COO)(3)](H2O)(3)CENTER-DOT-1.5H(2)O, Journal of alloys and compounds, 277, 1998, pp. 50-53
Citations number
4
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
277
Year of publication
1998
Pages
50 - 53
Database
ISI
SICI code
0925-8388(1998)277:<50:ANHM-G>2.0.ZU;2-S
Abstract
The reaction in gel of Gd(III) ions with TMA(3-), where TMA(3-) stands for [C6H3(COO)(3)](3-), has afforded single crystals of a bidimension al molecular compound formulated as Gd[TMA(H2O)(3)]. 1.5H(2)O whose cr ystal structure is reported here: C2/c, a = 20.454(2) Angstrom, b = 9. 973(1) Angstrom, c = 15.251(2) Angstrom, beta = 125.68(1)degrees and Z = 8. The structure consists of parallel double-sheet networks based o n honeycomb-like motifs based on Gd(III) ions and TMA(3-) groups. This compound exhibits a paramagnetic behaviour in the whole temperature r ange (2-300 K). (C) 1998 Elsevier Science S.A.