In sedimentary apatite two types of uranyl were observed, sorption of
uranyl aquecomplexes and films of uranyl minerals. Tetravalent uranium
is detected by the weak reabsorption lines. Hexavalent uranium was de
tected after oxidizing thermal treatment at 1100 K, as concentrated in
fluorite phase which is formed as result of heating. Uranyl luminesce
nce is absent in magmatic apatites before and after oxidizing heating,
indicating that the main form is due to tetravalent uranium. (C) 1998
Elsevier Science S.A.