LANTHANIDE IONS AS TEMPLATES FOR THE SYNTHESIS OF NEW DINUCLEAR OCTADENTATE SCHIFF-BASE COMPLEXES OF PODATE TYPE

Authors
PATRONIAKKRZYMINIEWSKA V RADECKAPARYZEK W
Citation
V. Patroniakkrzyminiewska et W. Radeckaparyzek, LANTHANIDE IONS AS TEMPLATES FOR THE SYNTHESIS OF NEW DINUCLEAR OCTADENTATE SCHIFF-BASE COMPLEXES OF PODATE TYPE, Journal of alloys and compounds, 277, 1998, pp. 822-826
Citations number
28
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
277
Year of publication
1998
Pages
822 - 826
Database
ISI
SICI code
0925-8388(1998)277:<822:LIATFT>2.0.ZU;2-J
Abstract
The template reactions of 2,6-diacetylpyridine with 1,12-diamine-4,9-d ioxadodecane in the presence of lanthanide ions produce octadentate ma croacyclic complexes of pedate type with terminal acetylpyridyl groups and a N4O4 set of donor atoms as a result of [2+1] Schiff base conden sation. The complexes were characterized by spectral data (IR, UV-vis, H-1-NMR, FAB-MS) and thermogravimetric and elemental analysis. (C) 19 98 Published by Elsevier Science S.A.