Wx. Zhang et al., CATALYTIC-OXIDATION OF CO AT AMBIENT-TEMPERATURE AND HUMIDITY ON AU NIO PREPARED BY USING DIFFERENT METHODS/, Gaodeng xuexiao huaxue xuebao, 19(8), 1998, pp. 1317-1319
The activities and durability of the oxidation of CO at ambient temper
ature and humidity on nanometer Au/NiO prepared by using different met
hods were studied, It was found that the activities and durability of
the catalysts were greatly changed with the preparation methods and ca
lcining temperature, Active and durable catalyst can be obtained by ca
reful control of the preparation procedures. Among the samples tested,
Au/NiO prepared by the following conditions-Na2CO3 solution was added
into an aqueous solution of Ni(NO3)(2), HAuCl4 and dodecylbenzene sul
fonic acid sodium salt (DBS), the resultant precipitate was heated to
70 degrees C and washed with deionized hot water of 70 degrees C, foll
owed by drying at room temperature for 48 h, and then the precipitate
was calcined at 300 degrees C-showed the highest activity and durabili
ty, it was even able to oxidize CO completely at 20 degrees C in the p
resence of 1.8% water vapor for 27 h.