THE CURING THEORY OF A(F) TYPE FREE-RADICAL HOMOPOLYMERIZATION (I) - DISTRIBUTION FUNCTION AND ITS INVARIANT PROPERTY

Citation
Hj. Wang et al., THE CURING THEORY OF A(F) TYPE FREE-RADICAL HOMOPOLYMERIZATION (I) - DISTRIBUTION FUNCTION AND ITS INVARIANT PROPERTY, Gaodeng xuexiao huaxue xuebao, 19(8), 1998, pp. 1329-1334
Citations number
24
Categorie Soggetti
Chemistry
ISSN journal
02510790
Volume
19
Issue
8
Year of publication
1998
Pages
1329 - 1334
Database
ISI
SICI code
0251-0790(1998)19:8<1329:TCTOAT>2.0.ZU;2-2
Abstract
By means of the polymer statistical theory, the sol fraction, gelation condition for the A(f) type free radical homopolymerization reaction are deduced. Furthermore, the number fraction distribution is obtained by means of the Lagrange expansion technique and the invariant proper ty of this distribution is revealed. This invariant property make the characterization of average polymer quantities for postgel easier.