A SANDWICH COMPLEX OF LITHIUM-OXIDE - (LI[(BUC)-C-N(NBUT)(2)])(4).LI2O

Citation
T. Chivers et al., A SANDWICH COMPLEX OF LITHIUM-OXIDE - (LI[(BUC)-C-N(NBUT)(2)])(4).LI2O, Journal of the Chemical Society. Dalton transactions, (16), 1998, pp. 2603-2605
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03009246
Issue
16
Year of publication
1998
Pages
2603 - 2605
Database
ISI
SICI code
0300-9246(1998):16<2603:ASCOL->2.0.ZU;2-C
Abstract
Hydrolysis of {Li[(BuC)-C-n(NBut)(2)]}(2), prepared from LiBun and (Bu NCNBut)-N-t in hexanes, produced the nineteen atom cluster {Li[(BuC)-C -n(NBut)(2)]}4 . Li2O; an X-ray structure determination revealed an Li 2O molecule encapsulated by two eight-membered Li2N4C2 rings.