F. Montalenti et R. Ferrando, COMPETING MECHANISMS IN ADATOM DIFFUSION ON A CHANNELED SURFACE - JUMPS VERSUS METASTABLE WALKS, Physical review. B, Condensed matter, 58(7), 1998, pp. 3617-3620
It is shown, by molecular-dynamics simulations, that in-channel Au ada
tom diffusion on missing-row reconstructed Au(110) takes place by two
different mechanisms, jumps and metastable walks. In a metastable walk
the adatom climbs up one of the (111) facets of the channel, diffuses
fast along the network of metastable minima an that facet, and finall
y is trapped again at the channel bottom. A considerable fraction of t
he events giving direct mass transport to distant cells occurs by this
new mechanism.