STEREOELECTRONIC CONTROL OF COPE REARRANGEMENT ENERGETICS THROUGH REMOTE DOUBLE-BONDS IN NOVEL, RIGID POLYCYCLIC FRAMES

Authors
MEHTA G REDDY SHK PATTABHI V BHANUMATHI S PRAMANIK A CHANDRASEKHAR J
Citation
G. Mehta et al., STEREOELECTRONIC CONTROL OF COPE REARRANGEMENT ENERGETICS THROUGH REMOTE DOUBLE-BONDS IN NOVEL, RIGID POLYCYCLIC FRAMES, Journal of the Chemical Society. Perkin transactions. I, (14), 1993, pp. 1539-1541
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
14
Year of publication
1993
Pages
1539 - 1541
Database
ISI
SICI code
0300-922X(1993):14<1539:SCOCRE>2.0.ZU;2-4
Abstract
The presence and orientation of remote double bonds are shown to compl etely alter the shapes of Cope rearrangement energy profiles in a hept acyclic system.