REGIO-SPECIFIC AND STEREO-SPECIFIC SYNTHESIS OF CIS-(+ -)-1-ACETOXY-4-(ACETOXYMETHYL)CYCLOPENT-2-ENE - A KEY INTERMEDIATE IN THE SYNTHESIS OF CARBOCYCLIC NUCLEOSIDES AND PSEUDO-RIBOFURANOSES/

Authors
HODGSON DM WITHERINGTON J MOLONEY BA
Citation
Dm. Hodgson et al., REGIO-SPECIFIC AND STEREO-SPECIFIC SYNTHESIS OF CIS-(+ -)-1-ACETOXY-4-(ACETOXYMETHYL)CYCLOPENT-2-ENE - A KEY INTERMEDIATE IN THE SYNTHESIS OF CARBOCYCLIC NUCLEOSIDES AND PSEUDO-RIBOFURANOSES/, Journal of the Chemical Society. Perkin transactions. I, (14), 1993, pp. 1543-1544
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
14
Year of publication
1993
Pages
1543 - 1544
Database
ISI
SICI code
0300-922X(1993):14<1543:RASSOC>2.0.ZU;2-8
Abstract
The synthesis of s-(+/-)-1-acetoxy-4-(acetoxymethyl)cyclopent-2-ene 1 from cyclopent-3-ene-1-carboxylic acid 2 by way of bromolactonisation, reductive ring opening and diacylation with in situ elimination of HB r is described.