ADDITIONS OF ELECTROPHILIC RADICALS TO ELECTRON-RICH ALKENES BY THE ATOM-TRANSFER METHOD - SURMOUNTING POTENTIALLY REVERSIBLE RADICAL ATOM-TRANSFER REACTIONS BY IRREVERSIBLE IONIC REACTIONS
Dp. Curran et Sb. Ko, ADDITIONS OF ELECTROPHILIC RADICALS TO ELECTRON-RICH ALKENES BY THE ATOM-TRANSFER METHOD - SURMOUNTING POTENTIALLY REVERSIBLE RADICAL ATOM-TRANSFER REACTIONS BY IRREVERSIBLE IONIC REACTIONS, Tetrahedron letters, 39(37), 1998, pp. 6629-6632
Conditions have been developed for the atom transfer radical addition
reaction of bromoesters to enol ethers. The putative intermediate halo
ethers are allowed to ionize and the resulting cations are trapped by
addition or elimination reactions. (C) 1998 Elsevier Science Ltd. All
rights reserved.