BETA-PINENE-6-ONE - A PIVOTAL SYNTHETIC INTERMEDIATE

Citation
D. Hebrault et D. Uguen, BETA-PINENE-6-ONE - A PIVOTAL SYNTHETIC INTERMEDIATE, Tetrahedron letters, 39(37), 1998, pp. 6699-6702
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
39
Issue
37
Year of publication
1998
Pages
6699 - 6702
Database
ISI
SICI code
0040-4039(1998)39:37<6699:B-APSI>2.0.ZU;2-O
Abstract
Submitting the title ketone to either acetoxymercuration or basic cond itions resulted in the formation of the acid beta-5 and alpha-5, respe ctively, with an useful selectivity, related rearrangements being obse rved by using the corresponding alcohol and its epoxy derivative. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.