L. Juha et al., FAST DEGRADATION OF FULLERENES BY ULTRAVIOLET-LASER RADIATION, Applied physics. B, Photophysics and laser chemistry, 57(1), 1993, pp. 83-84
The first observation of fullerene C60 ultraviolet photolysis in hexan
e solution was published two years ago 1!. Similar further experiment
s realized with an ultraviolet lamp and solar light gave inconsistent
results with ambiguous interpretations. We report the unexpectedly fas
t and efficient degradation of the fullerenes in n-hexane solutions, i
nduced by an XeCl-excimer laser. Well-defined experimental conditions
and good reproducibility in these experiments allow us to estimate the
minimal value of the quantum yield of fullerene photolysis.