ISOLATION OF (-FUSICOCCA-2,10(14)-DIENE, A 5-8-5-TRICYCLIC DITERPENE HYDROCARBON BIOSYNTHETICALLY RELATED TO THE FUSICOCCIN AGLYCON FROM FUSICOCCUM-AMYGDALI AND CONFIRMATION OF ITS STRUCTURE BY TOTAL SYNTHESIS())

Authors
KATO N ZHANG CS MATSUI T IWABUCHI H MORI A BALLIO A SASSA T
Citation
N. Kato et al., ISOLATION OF (-FUSICOCCA-2,10(14)-DIENE, A 5-8-5-TRICYCLIC DITERPENE HYDROCARBON BIOSYNTHETICALLY RELATED TO THE FUSICOCCIN AGLYCON FROM FUSICOCCUM-AMYGDALI AND CONFIRMATION OF ITS STRUCTURE BY TOTAL SYNTHESIS()), Journal of the Chemical Society. Perkin transactions. I (Print), (16), 1998, pp. 2473-2474
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I (Print) → ACNP
ISSN journal
0300922X
Issue
16
Year of publication
1998
Pages
2473 - 2474
Database
ISI
SICI code
0300-922X(1998):16<2473:IO(A5D>2.0.ZU;2-5
Abstract
(+)-Fusicocca-2,10(14)-diene, a double bond isomer of the putative fus icoccin biosynthetic intermediate, i.e., fusicocca-1,10(14)-diene, was isolated for the first time as a main hydrocarbon constituent from th e fusicoccin-producing fungus Fusicoccum amygdali, and its stereostruc ture including absolute configuration was unambiguously confirmed by t otal synthesis.