Td. Clarke et Cm. Wai, SELECTIVE REMOVAL OF CESIUM FROM ACID-SOLUTIONS WITH IMMOBILIZED COPPER FERROCYANIDE, Analytical chemistry (Washington), 70(17), 1998, pp. 3708-3711
Copper ferrocyanide can be immobilized on Chelex-20, a technical grade
chelating resin, for selective removal of cesium from neutral to acid
ic solutions. The immobilized copper ferrocyanide is much easier to ha
ndle than the copper ferrocyanide powder in extraction and separation
of cesium from aqueous solutions. In the presence of a reducing agent
such as hydrazine, the immobilized copper ferrocyanide resin is able t
o remove 98% of the cesium from a simulated acid waste solution in one
cycle of batch experiments. The resin shows promising properties for
remediation of acidic nuclear wastes and for concentration of Cs-137 f
rom environmental samples for quantitative analysis.