SELECTIVE REMOVAL OF CESIUM FROM ACID-SOLUTIONS WITH IMMOBILIZED COPPER FERROCYANIDE

Authors
Citation
Td. Clarke et Cm. Wai, SELECTIVE REMOVAL OF CESIUM FROM ACID-SOLUTIONS WITH IMMOBILIZED COPPER FERROCYANIDE, Analytical chemistry (Washington), 70(17), 1998, pp. 3708-3711
Citations number
9
Categorie Soggetti
Chemistry Analytical
ISSN journal
00032700
Volume
70
Issue
17
Year of publication
1998
Pages
3708 - 3711
Database
ISI
SICI code
0003-2700(1998)70:17<3708:SROCFA>2.0.ZU;2-W
Abstract
Copper ferrocyanide can be immobilized on Chelex-20, a technical grade chelating resin, for selective removal of cesium from neutral to acid ic solutions. The immobilized copper ferrocyanide is much easier to ha ndle than the copper ferrocyanide powder in extraction and separation of cesium from aqueous solutions. In the presence of a reducing agent such as hydrazine, the immobilized copper ferrocyanide resin is able t o remove 98% of the cesium from a simulated acid waste solution in one cycle of batch experiments. The resin shows promising properties for remediation of acidic nuclear wastes and for concentration of Cs-137 f rom environmental samples for quantitative analysis.