A FACILE ROUTE TO STEROIDAL 6-DEOXY-ALPHA-L-ALLOPYRANOSIDES

Authors
VANHEERDEN FR DIXON JT HOLZAPFEL CW
Citation
Fr. Vanheerden et al., A FACILE ROUTE TO STEROIDAL 6-DEOXY-ALPHA-L-ALLOPYRANOSIDES, Synthetic communications, 28(18), 1998, pp. 3345-3357
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
18
Year of publication
1998
Pages
3345 - 3357
Database
ISI
SICI code
0039-7911(1998)28:18<3345:AFRTS6>2.0.ZU;2-P
Abstract
The synthesis of a steroidal 6-deoxy-alpha-L-allopyranoside from chole stanol and rhamnose is described. The crucial steps in the reaction se quence comprised the transformation of a pseudoglycal into the more st eric hindered 2,3-cis-diol via an intermediate bromohydrin.