SELECTIVE AND HIGH-YIELD ELECTROSYNTHESIS OF (SILYL AND SILANYLENE 1-METHYLPYRROLES) FROM 1-METHYLPYRROLE BROMIDES

Authors
MOREAU C SEREINSPIRAU F BORDEAU M BIRAN C
Citation
C. Moreau et al., SELECTIVE AND HIGH-YIELD ELECTROSYNTHESIS OF (SILYL AND SILANYLENE 1-METHYLPYRROLES) FROM 1-METHYLPYRROLE BROMIDES, Synthetic communications, 28(18), 1998, pp. 3403-3414
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
18
Year of publication
1998
Pages
3403 - 3414
Database
ISI
SICI code
0039-7911(1998)28:18<3403:SAHEO(>2.0.ZU;2-4
Abstract
The sacrificial anode technique proved to be efficient for the selecti ve and competitive silylation of 1-methylpyrrole bromides with trimeth ylchlorosilane and diorganodichlorosilanes. Linear and cyclic alternat ed 1-methyl-pyrrolylene-silanylene oligomers were obtained in good to high yields.