SODIUM TRIMETHYL SILANOATE - A HYDROXYL SYNTHON FOR FLUORIDE SNAR TYPE DISPLACEMENTS FROM ANTHRACENE-9,10-DIONES, BENZ[G]ISOQUINOLINE-5-10-DIONES AND NITROBENZENES
Ap. Krapcho et D. Waterhouse, SODIUM TRIMETHYL SILANOATE - A HYDROXYL SYNTHON FOR FLUORIDE SNAR TYPE DISPLACEMENTS FROM ANTHRACENE-9,10-DIONES, BENZ[G]ISOQUINOLINE-5-10-DIONES AND NITROBENZENES, Synthetic communications, 28(18), 1998, pp. 3415-3422
Treatment of fluoroanthracene-9,10-diones, fluorobenz[g]isoquinoline-5
,10-diones and 1- or 4-fluoronitrobenzenes with sodium trimethylsilano
ate in THF followed by acidification readily yields the corresponding
hydroxyl analogues.