SYNTHESIS OF NEW MACROBICYCLIC HEXAAMIDE LIGANDS

Authors
MO ZL YANG W GAO JZ CHEN H GONG QJ HOU JG KANG JW
Citation
Zl. Mo et al., SYNTHESIS OF NEW MACROBICYCLIC HEXAAMIDE LIGANDS, Synthetic communications, 28(18), 1998, pp. 3503-3508
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
28
Issue
18
Year of publication
1998
Pages
3503 - 3508
Database
ISI
SICI code
0039-7911(1998)28:18<3503:SONMHL>2.0.ZU;2-K
Abstract
A new two-step synthesis method of macrobicyclic hexaamide ligands LH6 (I and II) with double condensation of triethyl nitrilotriacetate and 1,4(1,2)-diaminobenzene was developed. The cyclization does not requi re high dilution and template techniques. Two new hexaamide ligands we re prepared in good yields according to the proposed method.