L. Nunez et F. Cusso, POLARIZED ABSORPTION AND ENERGY-LEVELS OF LINBO3TM AND LINBO3(MGO)TM, Journal of physics. Condensed matter, 5(30), 1993, pp. 5301-5312
The polarized absorption spectra of Tm3+ ions in LiNbO3 and LiNbO3(MgO
) CryStalS, at 20 K, are presented. The Stark levels of the different
multiplets up to 28000 cm-1 are identified. The results are consistent
with C3 Symmetry for the rare-earth ions and a singlet (A) character
for the lower Stark level of the ground state. Several transitions sho
w additional structure, which indicates multi-site occupancy for the T
m3+ ions. The effect of MgO codoping, which includes the appearance of
new absorption bands, is also discussed.