PALLADIUM(0) ALLYLIC ALKYLATION IN A 2-PHASE SYSTEM OR WITH A SUPPORTED AQUEOUS-PHASE CATALYST

Authors
CHOPLIN A DOSSANTOS S QUIGNARD F SIGISMONDI S SINOU D
Citation
A. Choplin et al., PALLADIUM(0) ALLYLIC ALKYLATION IN A 2-PHASE SYSTEM OR WITH A SUPPORTED AQUEOUS-PHASE CATALYST, Catalysis today, 42(4), 1998, pp. 471-478
Citations number
31
Categorie Soggetti
Engineering, Chemical","Chemistry Applied","Chemistry Physical
Journal title
Catalysis today → ACNP
ISSN journal
09205861
Volume
42
Issue
4
Year of publication
1998
Pages
471 - 478
Database
ISI
SICI code
0920-5861(1998)42:4<471:PAAIA2>2.0.ZU;2-D
Abstract
The reaction of allylic carbonates with various acyclic and cyclic car bonucleophiles is catalyzed by the system Pd(OAc)(2) and P(C6H4-m-SO3N a)(3) (or tppts) in a two-phase liquid medium H2O-nitrile, the activit y of the catalyst depending mainly on the nature of the nitrile, the t emperature of the reaction and the ratio palladium/tppts. The same sys tem Pd(OAc)(2) and P(C6H4-m-SO3Na)(3) supported on silica catalyzes al so this reaction. The formation of the active palladium species in the two cases is followed by P-31 NMR spectroscopy and discussed. Publish ed by Elsevier Science B.V.